10 Sulfates

10.1 Anhydrite

Occurrence—Anhydrite is typically found in evaporite or metaevaporite deposits. It may also be found in amygdules or cracks in basalt, as a minor mineral in hydrothermal deposits, and in hot spring deposits.

Distinguishing Features—Anhydrite is generally colorless with anhedral to subhedral crystals in fine- to medium-grained aggregates. It has moderate relief which varies a bit with stage rotation. Anhydrite is orthorhombic and has three cleavages that intersect at 90°; two are visible in most thin-section views.

Anhydrite has high birefringence; maximum interference colors are 3rd-order green. Polysynthetic twinning is commonly seen under crossed polars (Fig 10.1.2).

Similar Minerals—Anhydrite is found in some of the same kind of rocks as gypsum, but has higher relief and stronger birefringence.

anhydrite

Optical Properties
■ Orthorhombic; biaxial (+)
2V = 42°
■ α = 1.570, β = 1.576, γ = 1.614
■ δ = 0.044; interference colors range up to 3rd-order
■ Extinction is parallel to cleavages
■ Twinning is common

Fig 10.1.1 Anhydrite

Abundant coarse anhydrite that displays twinning in both the PP and XP views. Interference colors range up to 3rd-order green. Photos from blogs.nvcc.edu.

■ Larger photos: PP XP

Fig 10.1.2 Anhydrite

Anhydrite that shows up to high 2nd-order interference colors. Polysynthetic twinning extends in two directions (XP). Photos from alexstrekeisen.it. FOV = 7 mm.

■ Larger photos: PP XP

Fig 10.1.3 Anhydrite

This is a view of an anhydrite-rich rock from the Windsor Group, a sequence of rock salt, rock anhydrite, and siltstone in Nova Scotia. It is mostly anydrite, but the specimen contains two grains of calcite that show higher relief than anhydrite in the PP view. Both minerals are colorless. In XP light, the anhydrite shows 2nd-order colors; calcite’s interference colors are hard to discern because they are very high-roder and washed out, and the largest calcite grain appears gray.

■ Larger photos: PP XP

Fig 10.1.4 Anhydrite

This view is almost all colorless cloudy anhydrite. It appears as coarse sheaves, radiating flakes, and fibers. The coarse grains show strong 2nd- and 3rd-order interference colors. Photos from alexstrekeisen.it. FOV = 7 mm.

■ Larger photos: PP XP

 

Fig 10.1.5 Anhydrite with Calcite

This rock contains anhydrite and calcite. The anhydrite is colorless; the calcite is grayish in the PP view. Under crossed polars, the anhydrite displays up to 3rd-order interference colors. Calcite’s colors are higher-order but it is unclear just how high. FOV = 7 mm. Photos from alexstrekeisen.it.

■ Larger photos: PP XP
Fig 10.1.6 Anhydrite

This view is entirely anhydrite; the rock is from near Balmat, New York. Some bubbles left over from poor thin-sectioning are also present. The anhydrite displays poorly-developed pseudocubic cleavage and shows little color in the PP view. In XP, it shows up to low 3rd-order interference colors and displays parallel extinction. Twins can be seen in both the PP and XP view, which is unusual for most minerals. FOV = 3.5 mm.

■ Larger photos: PP XP

10.2 Barite

Occurrence—Barite occurs most commonly as a minor mineral in hydrothermal veins. It is also found in veins in limestone, and as residual masses in clays.

Distinguishing Features—Barite is colorless, and has high relief. Granular aggregates are typical; rare individual crystals are elongate orthorhombic prisms. It has two perfect cleavages that intersect at 90o. A third, imperfect, cleavage is sometimes visible. Polysynthetic twinning is possible but rare.
Barite has low birefringence and interference colors.

barite

Similar Minerals—Barite is hard to distinguish from celestite, another sulfate, although celestite has a greater 2V.

Optical Properties
■ Orthorhombic; biaxial (+)
2V = 26° to 38°
■ α = 1.636, β = 1.637, γ = 1.648
■ δ = 0.012; interference colors are typically 1st-order gray or white, occasionally yellow or orange
■ Extinction is parallel to the best cleavage, but not to all cleavages

Fig 10.2.1 Barite

This field of view is entirely barite. It is colorless in PP and displays only 1st-order gray and white interference colors in XP. Photos from microckscopic.ro. FOV = 2 mm.

■ Larger photos: PP XP

Fig 10.2.2 Barite

Gray radiating and somewhat plumose barite. Although barite normally displays a maximum of 1st-order yellow interference colors. this specimen shows some higher-order blue colors. Photos from alexstrekeisen.it. FOV = 7 mm.

■ Larger photos: PP XP

Fig 10.2.3 Barite Quartz Vein

Barite occurs as prismatic (elongated) crystals in this rock from a hydrothermal vein deposit near Leverett, Massachusetts. The rest of the vein consists of quartz.  The quartz has lower relief and is generally clear compared with the grayish barite. It is clouded in places with fluid and other inclusions. In XP, the barite, like quartz, has low 1st-order interference colors. Some barite crystals show simple twins. This vein formed at temperatures around 200°C or below from fluids associated with the adjacent Mesozoic rift valley. FOV = 2.5 mm.

■ Larger photos: PP XP

Fig 10.2.4 Barite with Chabazite

This rock from central Nova Scotia, contains moderate-relief, colorless barite (BaSO4), moderate-relief, slightly brownish dolomite, and low-relief, colorless chabazite (chabazite group zeolite), developed as a crust on altered dark brown to black basalt (PP). In XP, the barite shows 1st-order gray to white intereference colors, dolomite is characteristically pearly gray to pastel. Chabazite’s interference colors are so low that the mineral appears almost isotropic. FOV = 8 mm.

■ Larger photos: PP XP

10.3 Gypsum

Occurrence—Massive gypsum is associated with evaporites. It is also found interlayered in limestones and shales, as fillings in fractures or holes in many sedimentary rocks, and as a gangue mineral or alteration product in some ore deposits.

Distinguishing Features—Gypsum is colorless and has low relief. It typically occurs as anhedral to subhedral aggregates, often with variable grain size. Less commonly, it is fibrous. It has one good cleavage and coarse crystals commonly cleave into parallel-sided plates or rhombs. Two other (poor) cleavages are sometimes seen. Polysynthetic twinning is common, sometimes created during thin section grinding.

Gypsum has low birefringence and display only 1st-order interference colors.

Similar Minerals—Gypsum is similar in some ways to anhydrite but has lower relief and birefringence. Brucite has higher relief.

gypsum

Optical Properties
■ Monoclinic; biaxial (+)
2V = 58°
■ α = 1.520, β = 1.523, γ = 1.530
■ δ = 0.010; maximum colors are first-order weak yellow
■ Extinction is parallel to the best cleavage but not to all cleavages
■ Cleavage angle is about 65o when two cleavages are present

Fig 10.3.1 Gypsum

Gypsum in a rock from the Lykins Fm in Colorado. The gypsum is mostly colorless in the PP view. In the XP view, interference colors range up to 1st-order white. FOV = 3.5 mm.

■ Larger photos: PP XP

Fig 10.3.2 Gypsum

Gypsum from Pomaia, Italy. The gypsum is colorless (PP) and shows mostly up to 1st-order white interference colors; a few grains give a hint of yellow interference colors. FOV = 1.5 mm.

■ Larger photos: PP XP

Fig 10.3.3 Gypsum

This is a scan of an entire thin section that is all gypsum. Gypsum is often colorless, but this sample appears somewhat stained (PP). In the XP view, the gypsum shows typical 1st-order colors. Photos from blogs.nvcc.edu.

■ Larger photos: PP XP

Fig 10.3.4 Gypsum

This view is entirely gypsum. Grain size is bimodal. The interference colors are 1st-order but the larger grains, which are probably thicker, show higher-order colors than the smaller grains.

■ Larger photos: PP XP

Fig 10.3.5 Gypsum with Anhydrite

This sample from Roccastrada, Italy, contains high-relief anhydrite and lower-relief gypsum. Both are colorless in the PP view and show twins in XP. In XP, the gypsum shows up to 1st-order gray and white interference colors; the anhydrite displays up to 2nd-order violet colors. FOV = 7 mm. Photos from alexstrekeisen.it.

■ Larger photos: PP XP

Fig 10.3.6 Gypsum with Calcite

Gypsum (colorless somewhat prismatic crystals with high relief) with calcite (gray to black) from the Presolana gypsum mine near Bergamo, Italy. Gypsum crystals appear zoned in both the PP and XP views with gray to black cores and in XP shows up to 1st-order gray interference colors. Coarse calcite in the upper right shows very high order interference colors; fine-grained calcite surrounds gypsum crystals. FOV = 7 mm. Photos from alexstrekeisen.it.

■ Larger photos: PP XP

 

 

Fig 10.3.7 Alabaster

This is alabaster, a rock composed entirely of fine-grained gypsum. Alabaster has historically been used for carving because gypsum is very soft. In the PP view, the gypsum grains are clear; in the XP view they show up to 1st-order yellow interference colors. Note the many bubbles that are present (due to poor thin section making). The rock comes from a quarry in Pomaia, Italy. FOV = 3.5 mm.

■ Larger photos: PP XP